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Chemistry
Combustion Analysis Calculator
Determine the empirical formula of an organic compound from combustion analysis data (CO₂ and H₂O produced).

Combustion Analysis Calculator

Determine the empirical formula of an organic compound from combustion analysis data. Enter the sample mass and the masses of CO₂ and H₂O produced to calculate the elemental composition and empirical formula.

Combustion analysis is a classical technique for determining the elemental composition of organic compounds. A known mass of the compound is burned completely in excess oxygen, and the masses of CO₂ and H₂O produced are measured.

How It Works:

  1. All carbon in the compound is converted to CO₂. Moles of C = moles of CO₂ = mass(CO₂) / 44.01.
  2. All hydrogen is converted to H₂O. Moles of H = 2 × moles of H₂O = 2 × mass(H₂O) / 18.015.
  3. If nitrogen is present, it is collected as N₂. Moles of N = 2 × moles of N₂.
  4. Oxygen is determined by difference: mass(O) = sample mass − mass(C) − mass(H) − mass(N).
  5. The mole ratios are reduced to the simplest whole numbers to give the empirical formula.

From Empirical to Molecular Formula:

The empirical formula gives the simplest ratio of atoms. To find the molecular formula, you need the actual molecular weight (from mass spectrometry or other methods). Molecular formula = n × empirical formula, where n = molecular weight / empirical formula weight.

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